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Communication
Chem. Commun., 2002, 2520 - 2521, DOI: 10.1039/b207568g
2D 4.82 Network with threefold parallel interpenetration from nanometer-sized tripodal ligand and lead(II) nitrate
Shuang-Yi Wan, Jian Fan, Taka-aki Okamura, Hui-Fang Zhu, Xing-Mei Ouyang, Wei-Yin Sun and Norikazu Ueyama
Reaction of nanometer-sized tripodal ligand 2,4,6-tris[4-(imidazol-1-ylmethyl)phenyl]-1,3,5-triazine (timpt) with lead(II) nitrate affords a novel polycatenated structure containing three interpenetrating 4.82 networks, in which the lead(II) atom has a hemidirected coordination geometry and a stereochemically active lone pair of electrons.
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